
This appears to be Daniel Hicks in 1851. He is living in the Romford Union Workhouse (apparently the same place his wife will be later in 1881). It has him listed as a 40(?) year old married "Pauper" that was previously a "Seaman". This fits with Annie's description of him being and invalid and a sailor.
I found a link giving information about the Romford Union Workhouse including pictures and a link to see who was there in 1881.